Step 1: Identify the constituents of Portland cement.
The important constituents of Portland cement are
\[
\mathrm{CaO,\ SiO_2,\ Al_2O_3,\ Fe_2O_3,\ MgO,\ SO_3.}
\]
Step 2: Count the compounds from the given list.
Present in Portland cement:
\[
\mathrm{MgO,\ CaO,\ Al_2O_3,\ SO_3,\ SiO_2,\ Fe_2O_3}
\]
Total number of compounds
\[
\boxed{6}
\]
Hence,
\[
\boxed{(A)}
\]
is the correct answer.