Question:

The n, l values possible for a sublevel with seven degenerate orbitals are respectively

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s(0): 1 orbital, p(1): 3, d(2): 5, f(3): 7. If orbitals = 7, then l must be 3.
  • 4, 3
  • 3, 4
  • 5, 1
  • 6, 2
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The Correct Option is A

Solution and Explanation

Step 1: Concept
The number of orbitals in a sublevel is given by the formula $(2l + 1)$.

Step 2: Meaning

Degenerate orbitals are orbitals within the same subshell that have the same energy.

Step 3: Analysis

Setting $2l + 1 = 7$ gives $2l = 6$, so $l = 3$. This corresponds to an 'f' subshell.

Step 4: Conclusion

For $l=3$ to exist, the principal quantum number $n$ must be at least $l+1 = 4$. Thus, the values are $n=4, l=3$. Final Answer: (A)
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