The problem asks us to find the frequency of collisions of oxygen molecules, given their mean free path and average speed at 300 K and 1 atm.
The frequency of molecular collisions \( f \) is related to the mean free path \( \lambda \) and the average speed \( \bar{c} \) by the formula:
\[ f = \frac{\bar{c}}{\lambda} \]where:
Step 1: Write down the given data.
\[ \lambda = 3 \times 10^{-7} \, \mathrm{m}, \quad \bar{c} = 600 \, \mathrm{m/s} \]Step 2: Use the formula for collision frequency:
\[ f = \frac{\bar{c}}{\lambda} \]Step 3: Substitute the given values into the formula.
\[ f = \frac{600}{3 \times 10^{-7}} \]Step 4: Simplify the expression.
\[ f = 2 \times 10^{9} \, \mathrm{s^{-1}} \]Therefore, the frequency of collisions of oxygen molecules is:
\[ \boxed{f = 2 \times 10^{9} \, \mathrm{s^{-1}}} \]Final Answer: The frequency of collisions is \(2 \times 10^{9} \, \mathrm{s^{-1}}\).
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)