Step 1: Concept
Packing fraction is the ratio of the volume occupied by particles to the total volume of the unit cell.
Step 2: Formula
For a diamond cubic structure, the packing efficiency is given by the formula:
$\text{Packing fraction} = \frac{\pi\sqrt{3}}{16}$
Step 3: Calculation
$\frac{\pi\sqrt{3}}{16} \approx 0.34$
Step 4: Conclusion
The maximum proportion of volume filled is 0.34 or 34%.
Final Answer: (B)