Question:

The major product obtained when benzene diazonium chloride is heated with water is:

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Important conversions: \[ Diazonium\ Salt \rightarrow Phenol \] upon heating with water. Always remember that nitrogen gas is liberated during the reaction.
Updated On: Jun 8, 2026
  • Chlorobenzene
  • Phenol
  • Benzaldehyde
  • Benzoic acid
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The Correct Option is B

Solution and Explanation

Concept: Diazonium salts undergo hydrolysis on heating with water. The diazonium group is replaced by hydroxyl group. This is a very important NCERT reaction.

Step 1:
Write the reaction.
\[ C_6H_5N_2^+Cl^- + H_2O \] \[ \xrightarrow{\Delta} C_6H_5OH + N_2 + HCl \]

Step 2:
Identify product.
The hydroxyl group replaces the diazonium group. Thus: \[ C_6H_5OH \] is produced.

Step 3:
Conclusion.
The final product is: \[ \boxed{\text{Phenol}} \]
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