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the major product formed in the following reaction
Question:
The major product formed in the following reaction
|
is
IIT JAM CY - 2024
IIT JAM CY
Updated On:
Jan 10, 2025
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The Correct Option is
B
Solution and Explanation
The reaction sequence involves a
nucleophilic substitution
followed by an
electrophilic addition
:
sec-BuLi
(sec-butyllithium) acts as a base, deprotonating the thiol group in the initial structure.
The
phenyl group
(Ph) attaches to the deprotonated site via the
bromine atom
(Br), forming an alkylated intermediate.
The intermediate undergoes a reaction with
mercury sulfate
(HgSO
4
) and
aqueous sulfuric acid
(H
2
SO
4
), facilitating the formation of a carbocation.
Finally, in the presence of
methanol
(MeOH) and BF
3
·Et
2
O, an
ether
(OCH
3
) group is added to the carbocation site, completing the transformation.
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