Concept:
Photosynthetic pigments absorb light energy and convert it into chemical energy during photosynthesis.
Among all pigments present in higher plants, chlorophyll
a is the primary pigment directly involved in the conversion of light energy.
Accessory pigments assist chlorophyll
a by absorbing light of different wavelengths.
Step 1: Identify the primary photosynthetic pigment.
The chief pigment responsible for photosynthesis is
\[
\boxed{\text{Chlorophyll a}}
\]
It is present in the reaction centres of both Photosystem I and Photosystem II.
Step 2: Understand the role of accessory pigments.
Other pigments include:
• Chlorophyll b
• Carotenoids
• Xanthophylls
These pigments absorb additional wavelengths of light and transfer the absorbed energy to chlorophyll
a.
Step 3: Analyse the options.
• Chlorophyll a is the primary pigment.
• Chlorophyll b is an accessory pigment.
• Carotenoids are accessory pigments.
• Phycobilins occur mainly in cyanobacteria and red algae.
Therefore,
\[
\boxed{\textbf{Option (A)}}
\]
is the correct answer.