Since:
\[
L_1 \parallel L_2
\]
and
\[
L_3 \parallel L_4
\]
angles formed between these parallel pairs follow corresponding and alternate angle properties.
Angle \(b^\circ\) on \(L_1\) with transversal \(L_3\) is equal to the corresponding angle made by \(L_4\) with \(L_2\).
Now in the figure, \(a^\circ\) and that corresponding angle lie on a straight line.
So:
\[
a+b=180^\circ
\]
Hence, they are:
\[
\boxed{\text{Supplementary}}
\]