The kinetic energies of an electron (\(e\)) and a proton (\(p\)) are \(E\) and \(3E\), respectively. Given that the mass of a proton is 1836 times that of an electron, the ratio of their de Broglie wavelengths (\(\lambda_e / \lambda_p\)) is ___________ (rounded off to two decimal places).
The de Broglie wavelength (\(\lambda\)) of a particle is given by the equation: \[ \lambda = \frac{h}{p} \] where \(h\) is Planck's constant and \(p\) is the momentum of the particle. The kinetic energy (\(K\)) of a particle is related to its momentum by: \[ K = \frac{p^2}{2m} \implies p = \sqrt{2mK} \] where \(m\) is the mass of the particle. For the electron (\(e\)), the kinetic energy is \(K_e = E\) and its mass is \(m_e\). The de Broglie wavelength of the electron is: \[ \lambda_e = \frac{h}{p_e} = \frac{h}{\sqrt{2m_e K_e}} = \frac{h}{\sqrt{2m_e E}} \] For the proton (\(p\)), the kinetic energy is \(K_p = 3E\) and its mass is \(m_p = 1836 m_e\). The de Broglie wavelength of the proton is: \[ \lambda_p = \frac{h}{p_p} = \frac{h}{\sqrt{2m_p K_p}} = \frac{h}{\sqrt{2(1836 m_e) (3E)}} = \frac{h}{\sqrt{11016 m_e E}} \] Now, we need to find the ratio of their de Broglie wavelengths (\(\lambda_e / \lambda_p\)): \[ \frac{\lambda_e}{\lambda_p} = \frac{\frac{h}{\sqrt{2m_e E}}}{\frac{h}{\sqrt{11016 m_e E}}} = \frac{\sqrt{11016 m_e E}}{\sqrt{2m_e E}} = \sqrt{\frac{11016 m_e E}{2m_e E}} \] \[ \frac{\lambda_e}{\lambda_p} = \sqrt{\frac{11016}{2}} = \sqrt{5508} \] \[ \sqrt{5508} \approx 74.2159 \] Rounding off to two decimal places, the ratio \(\lambda_e / \lambda_p\) is 74.22. This falls within the given range of 74.10 to 74.30.
An aqueous solution of Co(ClO4)2·6H2O is light pink in colour. Addition of conc. HCl results in an intense blue coloured solution due to the formation of a new species. The new species among the following is:

[Given: Atomic number of Co = 27]
Among the given options, the possible product(s) that can be obtained from the following reaction is/are:

Choose the correct option(s) with regard to mechanism of the following transformation.

what is the final product
intensity ratio of final product