Question:

The isobars of one mole of an ideal gas were obtained at three different pressures $(p_1, p_2$ and $p_3)$. The slopes of these isobars are $m_1, m_2$ and $m_3$ respectively. If $p_1<p_2<p_3$, then the correct relation of the slopes is

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For an ideal gas, an isobar is a graph of Volume (V) vs. Temperature (T) at constant pressure (P). The graph is a straight line through the origin ($V = (R/P)T$), and the slope is $R/P$. Remember that the slope of this graph is inversely proportional to the pressure.
Updated On: Mar 30, 2026
  • $m_1>m_2>m_3$
  • $m_1<m_2<m_3$
  • $m_1>m_3>m_2$
  • $m_1 = m_2 = m_3$
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The Correct Option is A

Solution and Explanation

Step 1: Write the equation of state for an ideal gas.
The ideal gas law is $PV = nRT$. We are given that $n=1$ mole, so $PV = RT$.

Step 2: Express the relationship for an isobar.
An isobar is a graph plotted at constant pressure ($P$). The graph is plotted with Volume ($V$) on the y-axis and Temperature ($T$) on the x-axis.
We rearrange the ideal gas law to express $V$ as a function of $T$: \[ V = \left(\frac{R}{P}\right) T. \]

Step 3: Determine the slope of the isobar.
The equation $V = \left(\frac{R}{P}\right) T$ is a straight line equation of the form $y = m x$, where $y=V$, $x=T$, and $m$ is the slope. The slope of the isobar is: \[ m = \frac{R}{P}. \]

Step 4: Relate the slopes to the given pressures.
We are given three different pressures, $p_1, p_2, p_3$, and their corresponding slopes $m_1, m_2, m_3$. \[ m_1 = \frac{R}{p_1}, m_2 = \frac{R}{p_2}, m_3 = \frac{R}{p_3}. \]

Step 5: Determine the relationship between the slopes.
We are given the pressure relationship $p_1<p_2<p_3$. Since the slope $m$ is inversely proportional to the pressure $P$ (i.e., $m \propto \frac{1}{P}$), a smaller pressure corresponds to a larger slope. Therefore, the order of the slopes must be the inverse of the order of the pressures. \[ p_1<p_2<p_3 \implies \frac{1}{p_1}>\frac{1}{p_2}>\frac{1}{p_3}. \] Multiplying by $R$ (which is a positive constant) maintains the inequality: \[ \frac{R}{p_1}>\frac{R}{p_2}>\frac{R}{p_3} \implies m_1>m_2>m_3. \]
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