Step 1: Understand Tollens' reagent.
Tollens' reagent is ammoniacal silver nitrate.
It contains:
\[
[Ag(NH_3)_2]^+
\]
Step 2: Identify what Tollens' reagent detects.
Tollens' reagent is used to detect aldehydes.
Aldehydes are easily oxidized to carboxylate ions.
During this process, silver ion is reduced to metallic silver.
Step 3: Write the observation.
When an aldehyde reacts with Tollens' reagent, a silver mirror is formed.
This is known as the silver mirror test.
\[
\ce{RCHO -> RCOO^-}
\]
\[
\ce{Ag+ -> Ag}
\]
Step 4: Final answer.
Therefore, Tollens' reagent identifies:
\[
\text{Aldehyde group}.
\]