Question:

The functional group that can be identified through Tollens' reagent test is:

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Tollens' reagent gives silver mirror test with aldehydes.
Updated On: May 4, 2026
  • Aldehyde
  • Alcoholic
  • Phenolic
  • Carboxylic acid
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The Correct Option is A

Solution and Explanation


Step 1: Understand Tollens' reagent.

Tollens' reagent is ammoniacal silver nitrate. It contains: \[ [Ag(NH_3)_2]^+ \]

Step 2: Identify what Tollens' reagent detects.

Tollens' reagent is used to detect aldehydes. Aldehydes are easily oxidized to carboxylate ions. During this process, silver ion is reduced to metallic silver.

Step 3: Write the observation.

When an aldehyde reacts with Tollens' reagent, a silver mirror is formed. This is known as the silver mirror test. \[ \ce{RCHO -> RCOO^-} \] \[ \ce{Ag+ -> Ag} \]

Step 4: Final answer.

Therefore, Tollens' reagent identifies: \[ \text{Aldehyde group}. \]
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