Concept:
Electron mobility (\(\mu\)) is defined as the drift velocity acquired by an electron per unit electric field.
Mathematically,
\[
\mu=\frac{v_d}{E}
\]
According to the free electron theory,
\[
v_d=\frac{eE\tau}{m},
\]
where
\[
e=\text{Charge of electron},
\]
\[
m=\text{Mass of electron},
\]
\[
\tau=\text{Relaxation time}.
\]
Substituting the expression of drift velocity into the mobility equation,
\[
\mu=\frac{e\tau}{m}.
\]
Hence,
\[
\boxed{\tau=\frac{\mu m}{e}}
\]
This relation is frequently used to determine the relaxation time of free electrons.
Step 1: Convert the given mobility into SI units.
Given,
\[
\mu=32~\text{cm}^{2}/\text{Vs}.
\]
Since,
\[
1~\text{cm}^{2}=10^{-4}\text{ m}^{2},
\]
therefore,
\[
32~\text{cm}^{2}
=32\times10^{-4}\text{ m}^{2}
=3.2\times10^{-3}\text{ m}^{2}.
\]
Hence,
\[
\boxed{\mu=3.2\times10^{-3}\text{ m}^{2}/\text{Vs}}.
\]
Step 2: Write the formula for relaxation time.
The relation between mobility and relaxation time is
\[
\mu=\frac{e\tau}{m}.
\]
Rearranging,
\[
\tau=\frac{\mu m}{e}.
\]
Step 3: Substitute the given values.
Given,
\[
\mu=3.2\times10^{-3}\text{ m}^{2}/\text{Vs},
\]
\[
m=9.1\times10^{-31}\text{ kg},
\]
\[
e=1.6\times10^{-19}\text{ C}.
\]
Therefore,
\[
\tau
=
\frac{(3.2\times10^{-3})(9.1\times10^{-31})}
{1.6\times10^{-19}}.
\]
First, multiply the numerator,
\[
3.2\times9.1
=29.12,
\]
thus,
\[
\tau
=
\frac{29.12\times10^{-34}}
{1.6\times10^{-19}}.
\]
Now divide,
\[
\frac{29.12}{1.6}
=18.2.
\]
Hence,
\[
\tau
=
18.2\times10^{-15}
=
1.82\times10^{-14}\;s.
\]
Therefore,
\[
\boxed{\tau=1.82\times10^{-14}\;s.}
\]
Thus, the correct answer is
\[
\boxed{\textbf{Option (C)}}.
\]
Important Observation:
The value obtained using the given data is
\[
\boxed{1.82\times10^{-14}\;s.}
\]
\[
\boxed{\textbf{Option (C)}}.
\]