{Threshold Wavelength}: The threshold wavelength is the longest wavelength of light that can eject electrons from a metal surface. It is inversely proportional to the work function of the metal. A lower work function results in a longer threshold wavelength.
The threshold wavelength (\( \lambda_{\text{threshold}} \)) for a metal surface is related to its work function (\( \phi \)) by the equation:
\[ \lambda_{\text{threshold}} = \frac{hc}{\phi} \]where:
Given:
\[ hc = 1242 \, \text{eV nm} \] \[ \phi_A = 9 \, \text{eV} \] \[ \phi_B = 4.5 \, \text{eV} \]Step 1: Calculate Threshold Wavelengths for Both Metals
For Metal A:
\[ \lambda_{\text{threshold}, A} = \frac{1242 \, \text{eV nm}}{9 \, \text{eV}} = 138 \, \text{nm} \]For Metal B:
\[ \lambda_{\text{threshold}, B} = \frac{1242 \, \text{eV nm}}{4.5 \, \text{eV}} = 276 \, \text{nm} \]Step 2: Determine the Difference Between Threshold Wavelengths
\[ \Delta \lambda = \lambda_{\text{threshold}, B} - \lambda_{\text{threshold}, A} = 276 \, \text{nm} - 138 \, \text{nm} = 138 \, \text{nm} \]Therefore, the difference between the threshold wavelengths for metal surfaces A and B is 138 nm, which corresponds to option (4).
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)