Question:

The correct order of metallic radius of Al, Ga, In, Tl is

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Remember anomaly: Gallium is slightly smaller than aluminium because of d-block contraction.
Updated On: Jun 15, 2026
  • \(Tl& gt;In& gt;Al& gt;Ga\)
  • \(Tl& gt;In& gt;Ga& gt;Al\)
  • \(In& gt;Ga& gt;Al& gt;Tl\)
  • \(Ga& gt;In& gt;Tl& gt;Al\)
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The Correct Option is A

Solution and Explanation

Concept: Normally atomic radius increases down group. However due to d-block contraction and f-block contraction anomalies occur. Group 13 elements: \[ Al,Ga,In,Tl \] Expected increase downward but gallium becomes smaller than expected due to poor shielding by d electrons.

Step 1:
Observe periodic trend. Normally \[ Al& lt;Ga& lt;In& lt;Tl \] But d-block contraction affects gallium. Its size becomes slightly smaller than aluminium.

Step 2:
Apply d-block contraction effect. Gallium has filled 3d electrons. These electrons shield poorly. Effective nuclear charge increases. Radius decreases. Thus \[ Ga& lt;Al \]

Step 3:
Final order. Thus order becomes \[ Tl& gt;In& gt;Al& gt;Ga \] Correct option: \[ \boxed{A} \]
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