Step 1: Concept For a vector $\vec{V} = x\hat{i} + y\hat{j}$, the angle $\theta$ with the X-axis is given by $\tan \theta = y/x$.
Step 2: Meaning Here, the X-component ($x$) is 2 and the Y-component ($y$) is 2.
Step 3: Analysis $\tan \theta = 2/2 = 1$.
Step 4: Conclusion Since $\tan 45^{\circ} = 1$, the angle made with the X-axis is $45^{\circ}$.
Final Answer: (A)