Question:

Tarnishing of silver is due to formation of

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Silver tarnishes because of formation of black silver sulphide \((Ag_2S)\) on its surface.
  • Its sulphate layer
  • Its nitrate layer
  • Its sulphide layer
  • Its chloride layer
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The Correct Option is C

Solution and Explanation

Silver articles slowly become black when exposed to air. This black coating is called tarnish. Air may contain small amounts of hydrogen sulphide: \[ H_2S. \] Silver reacts with hydrogen sulphide to form silver sulphide: \[ Ag_2S. \] The reaction may be written as: \[ 2Ag+H_2S\rightarrow Ag_2S+H_2. \] The compound: \[ Ag_2S \] is black in colour. Therefore, tarnishing of silver is due to the formation of its sulphide layer.
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