Concept:
The work function \( \phi \) of a metal is inversely proportional to its threshold wavelength \( \lambda_0 \) according to Einstein's photoelectric equation:
\[
\phi = \frac{hc}{\lambda_0} \implies \lambda_0 \propto \frac{1}{\phi}
\]
Therefore, the ratio of the threshold wavelengths of two metals is equal to the inverse ratio of their work functions:
\[
\frac{\lambda_{01}}{\lambda_{02}} = \frac{\phi_2}{\phi_1}
\]
Step 1: Setting up the inverse work function ratio fraction.
From the question data:
• Work function of Sodium, \( \phi_1 = 2.3\,\text{eV} \)
• Work function of Copper, \( \phi_2 = 4.5\,\text{eV} \)
Applying the inverse relationship:
\[
\frac{\lambda_{\text{Na}}}{\lambda_{\text{Cu}}} = \frac{4.5}{2.3}
\]
Step 2: Evaluating the numerical value.
\[
\frac{4.5}{2.3} \approx 1.956 \approx 2
\]
Thus, the ratio of their threshold wavelengths is very nearly \( 2:1 \).