Step 1: The axilla is a pyramidal space between the upper arm and chest wall, with an apex, a base, and four walls (anterior, posterior, medial, and lateral).
Step 2: The posterior (subscapular) wall is formed by three muscles: subscapularis above, with teres major and latissimus dorsi below. So among the options, subscapularis is the correct posterior wall component.
Step 3: The other options belong to different walls. Pectoralis major and pectoralis minor form the anterior (pectoral) wall along with subclavius, and the intercostal muscles (with upper four ribs and serratus anterior) form the medial (thoracic) wall.
Step 4: Therefore, the posterior wall of the axilla is formed by subscapularis.