Concept:
Plaster of Paris is prepared from gypsum.
Gypsum is:
\[
CaSO_4 \cdot 2H_2O
\]
When gypsum is heated to about:
\[
100^\circ C
\]
it loses water molecules and forms Plaster of Paris.
Reaction:
\[
CaSO_4 \cdot 2H_2O
\rightarrow
CaSO_4 \cdot \frac{1}{2}H_2O + \frac{3}{2}H_2O
\]
Step 1: Identify the raw material.
Gypsum is hydrated calcium sulphate.
Formula:
\[
CaSO_4 \cdot 2H_2O
\]
Step 2: Understand preparation of Plaster of Paris.
On heating gypsum around:
\[
100^\circ C
\]
partial removal of water occurs and Plaster of Paris forms.
Step 3: Examine options carefully.
Option (A): \(0^\circ C\)
No heating.
Incorrect.
Option (B): \(200^\circ C\)
Too high.
Incorrect.
Option (C): \(50^\circ C\)
Insufficient heating.
Incorrect.
Option (D): \(100^\circ C\)
Correct temperature.
Correct.
Step 4: Select the correct answer.
Therefore, Plaster of Paris is obtained by heating gypsum at:
\[
\boxed{100^\circ C}
\]
Hence,
\[
\boxed{(4)\ 100^\circ C}
\]