Step 1: Understanding the Concept:
Doping semiconductors involves adding impurities. Trivalent impurities (Group 13) create P-type semiconductors, while Pentavalent impurities (Group 15) create N-type.
Step 2: Detailed Explanation:
* Trivalent (3 valence electrons): Boron (B), Aluminium (Al), Gallium (Ga), Indium (In).
* Pentavalent (5 valence electrons): Phosphorus (P), Arsenic (As), Antimony (Sb), Bismuth (Bi).
Antimony belongs to Group 15 and is therefore pentavalent.
Step 3: Final Answer:
The correct option is (b).