Write the correct order of rate of reaction of following compounds with $PhN_2Cl$
P: $N,N$-dimethylaniline
Q: $N,N$-dimethyl-3-methylaniline
R: $N,N$-dimethyl-2,6-dimethylaniline
Most preferred site for electrophilic substitution in above example?
(Note: The molecule contains a nitrogen-containing ring and a carbonyl-containing ring, labels are U, S, R, P).
| Column-I (Complex compound) | Column-II ($\Delta_0$ (CFSE) $\text{cm}^{-1}$) |
| (i) $[Cr(CN)_6]^{3-}$ | (P) 17000 |
| (ii) $[Cr(H_2O)_6]^{3+}$ | (Q) 15000 |
| (iii) $[Cr(en)_3]^{3+}$ | (R) 12000 |
| (iv) $[CrF_6]^{3-}$ | (S) 20000 |
Write the correct order of rate of reaction of following compounds with $PhN_2Cl$
P: $N,N$-dimethylaniline
Q: $N,N$-dimethyl-3-methylaniline
R: $N,N$-dimethyl-2,6-dimethylaniline
Most preferred site for electrophilic substitution in above example?
(Note: The molecule contains a nitrogen-containing ring and a carbonyl-containing ring, labels are U, S, R, P).
Assuming in forward bias condition there is a voltage drop of \(0.7\) V across a silicon diode, the current through diode \(D_1\) in the circuit shown is ________ mA. (Assume all diodes in the given circuit are identical) 
| Column-I (Complex compound) | Column-II ($\Delta_0$ (CFSE) $\text{cm}^{-1}$) |
| (i) $[Cr(CN)_6]^{3-}$ | (P) 17000 |
| (ii) $[Cr(H_2O)_6]^{3+}$ | (Q) 15000 |
| (iii) $[Cr(en)_3]^{3+}$ | (R) 12000 |
| (iv) $[CrF_6]^{3-}$ | (S) 20000 |