Water exhibits an anomalous expansion between 0$^{\circ}$C and 4$^{\circ}$C. Normally, most substances expand when heated and contract when cooled. However, water behaves differently in this specific temperature range. When water at 0$^{\circ}$C is heated, instead of expanding, it contracts until its temperature reaches 4$^{\circ}$C. Above 4$^{\circ}$C, it begins to expand like other substances. This means water has its maximum density at 4$^{\circ}$C.
The reasons for this anomaly are due to the unique hydrogen bonds in water. At temperatures below 4$^{\circ}$C, the water molecules arrange themselves in a more open hexagonal structure due to hydrogen bonding, which increases the volume and decreases the density of the water.