Step 1: Boyle's Law.
Boyle's Law relates pressure and volume, stating that at constant temperature, the volume of a gas is inversely proportional to the pressure. The formula for Boyle's Law is \( PV = \text{Constant} \), so it matches with option (III).
Step 2: Charles' Law.
Charles' Law states that the volume of a gas is directly proportional to its temperature, at constant pressure. The relation \( \frac{V}{T} = \text{Constant} \) corresponds to this, matching with option (I).
Step 3: Avogadro's Law.
Avogadro's Law states that the volume of a gas is directly proportional to the number of moles, which gives the relation \( V \propto n \), matching with option (IV).
Step 4: Graham's Law of Diffusion.
Graham's Law describes the relationship between the rates of diffusion of gases and their molar masses. The relation \( \frac{T_1}{T_2} = \frac{M_2}{M_1} \) corresponds to this, matching with option (II).
Step 5: Conclusion.
Thus, the correct matching is (A) - (I), (B) - (II), (C) - (III), and (D) - (IV), which corresponds to option (3).
Final Answer: \[ \boxed{\text{(3) (A) - (I), (B) - (II), (C) - (III), (D) - (IV)}} \]
(Zn + 4HNO_3 Zn(NO_3)_2 + 2H_2O + 2NO_2)
32.5 g of zinc reacts with concentrated nitric acid as given in the above equation.
(a) How many moles of zinc was required in the reaction?
(b) Find the mass of nitric acid needed to react with 32.5 g of zinc.
(c) Find the volume of nitrogen dioxide liberated in (b).
(Atomic weight: H = 1, N = 14, O = 16, Zn = 65)