Step 1: Recall each microstructure.
- Core–mantle structure: Large strained mineral grains (core) surrounded by fine recrystallized grains (mantle). → (2).
- Decussate texture: Randomly oriented mineral grains, common in sheet silicates (micas, chlorite). → (4).
- Spherulite: Radiating fibrous aggregates of minerals such as K-feldspar and quartz. → (1).
- Millipede structure: Inclusion trails in porphyroblasts curving into matrix foliation forming concave outward patterns. → (3).
Step 2: Match with options.
\[
P \to 2, \quad Q \to 4, \quad R \to 1, \quad S \to 3
\]
Final Answer:
\[
\boxed{\text{(C) P-2, Q-4, R-1, S-3}}
\]