Match the LIST-I with LIST-II
\[ \begin{array}{|l|l|} \hline \text{LIST-I} & \text{LIST-II} \\ \hline \text{A. Gravitational constant} & \text{I. } [LT^{-2}] \\ \hline \text{B. Gravitational potential energy} & \text{II. } [L^2T^{-2}] \\ \hline \text{C. Gravitational potential} & \text{III. } [ML^2T^{-2}] \\ \hline \text{D. Acceleration due to gravity} & \text{IV. } [M^{-1}L^3T^{-2}] \\ \hline \end{array} \]
Choose the correct answer from the options given below:
Let's match the quantities in LIST-I with their corresponding dimensional formulas in LIST-II. Understanding the quantities and their respective dimensional formulas is essential in solving this type of question.
The gravitational constant \(G\) is used in Newton's law of universal gravitation: \(F = \frac{G \cdot m_1 \cdot m_2}{r^2}\), where \(F\) is the gravitational force. The dimensional formula for \(G\) can be derived by rearranging the formula: \(G = \frac{F \cdot r^2}{m_1 \cdot m_2}\). Thus, its dimensional formula is \([M^{-1}L^3T^{-2}]\).
This is the energy due to position in a gravitational field, given by \(U = m \cdot g \cdot h\). Here, \(m\) is mass, \(g\) is acceleration due to gravity, and \(h\) is height. So, its dimensional formula is \([ML^2T^{-2}]\).
The gravitational potential at a point is defined as the work done per unit mass to bring a mass from infinity to that point: \(V = \frac{U}{m} = \frac{m \cdot g \cdot h}{m} = g \cdot h\). Its dimensional formula can be derived as \([L^2T^{-2}]\).
The acceleration due to gravity \(g\) is the acceleration experienced by an object due to the gravitational force. Its dimensional formula is derived from \(F = m \cdot g\), leading to \(g = \frac{F}{m}\). Hence, its dimensional formula is \([LT^{-2}]\).
By matching the descriptions and dimensional formulas, we get the correct answer: A-IV, B-III, C-II, D-I.
(A) \( G = \frac{Fr^2}{m^2} \) \( [G] = \frac{[MLT^{-2}][L^2]}{[M^2]} = [M^{-1}L^3T^{-2}] \) (IV)
(B) P.E. = mgh = \( [MLT^{-2}L] = [ML^2T^{-2}] \) (III)
(C) Gravitational Potential = \( \frac{GM}{r} \) \( [M^{-1}L^3T^{-2}] \frac{[M]}{[L]} = [M^0L^2T^{-2}] = [L^2T^{-2}] \) (II)
(D) Acceleration due to gravity = \( \frac{GM}{r^2} \) \( [M^{-1}L^3T^{-2}] \frac{[M]}{[L^2]} = [M^0LT^{-2}] = [LT^{-2}] \) (I)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)