Step 1: Glucagon. It is a peptide hormone secreted by $\alpha$-cells of pancreas. Hence, P $⇒$ (ii) – d.
Step 2: Pregnenolone. It is a steroid precursor formed in the adrenal glands. Hence, Q $⇒$ (iii) – c.
Step 3: FSH. Follicle-stimulating hormone is a glycoprotein hormone secreted by the anterior pituitary. Hence, R $⇒$ (iv) – a.
Step 4: Melatonin. Derived from tryptophan and secreted by the pineal gland. Hence, S $⇒$ (i) – b.
Thus, the correct matching is:
P – (ii) – d ; Q – (iii) – c ; R – (iv) – a ; S – (i) – b.