Step 1: Recall the physiological roles and deficiency symptoms.
\[
\boxed{
\begin{aligned}
\text{Manganese} &\rightarrow \text{Activates IAA oxidase} \rightarrow \text{Brown spots with chlorotic veins}
\text{Zinc} &\rightarrow \text{Needed for auxin synthesis} \rightarrow \text{Mottled leaf disease}
\text{Boron} &\rightarrow \text{Ca}^{2+}\text{ uptake and utilization} \rightarrow \text{Heart-rot in beets}
\text{Chlorine} &\rightarrow \text{Anion-cation balance} \rightarrow \text{Bronzing in legumes}
\end{aligned}
}
\]
Step 2: Match the lists.
\[
\boxed{
\begin{aligned}
\text{I} &\rightarrow D-P
\text{II} &\rightarrow C-Q
\text{III} &\rightarrow B-R
\text{IV} &\rightarrow A-S
\end{aligned}
}
\]
Step 3: Choose the correct option.
Hence, the correct option is
\[
\boxed{(D).}
\]