Step 1: Understand the Processes.
- The Hydrological cycle involves processes like infiltration and water movement through the Earth's systems.
- The Biogeochemical cycle refers to processes like ocean closure and denitrification, which relate to chemical elements cycling through Earth's biosphere, atmosphere, and lithosphere.
- The Rock cycle is the transformation of rocks from one form to another, such as regolith formation.
- The Wilson cycle involves ocean closure and plate tectonics, impacting the Earth's crust and mantle.
Step 2: Match the Correct Cycles and Processes.
- P (Hydrological cycle) matches with 3 (Infiltration) as water movement and infiltration are key components.
- Q (Biogeochemical cycle) matches with 4 (Denitrification) as it deals with nutrient cycling, including nitrogen.
- R (Rock cycle) matches with 1 (Regolith formation) as it involves the physical and chemical breakdown of rocks.
- S (Wilson cycle) matches with 2 (Ocean closure) as it is related to the tectonic process affecting oceanic plates.
Thus, the correct matching is:
\[
\boxed{\text{P-3, Q-4, R-1, S-2}}
\]