Explanation of Each Pair:
Glycogen → Animal starch (e)
Glycogen is a polysaccharide that stores energy in animals, hence called animal starch.
Sodium benzoate → Food preservative (c)
Widely used to preserve food and beverages due to antimicrobial properties.
2,4,6-trinitrophenol → Picric acid (a)
The chemical name of picric acid is 2,4,6-trinitrophenol.
\(K_4[Fe(CN)_6]\) → Secondary valency 6 (b)
In coordination compounds, iron has coordination number (secondary valency) 6.
Rate = \(K[A]^{3/2}[B]^{-1}\) → Half order (d)
Fractional powers indicate fractional order reactions; here overall order is fractional (includes half-order behavior).
Final Matching:
\[
\boxed{(i)-(e),\ (ii)-(c),\ (iii)-(a),\ (iv)-(b),\ (v)-(d)}
\]