To solve this question, we need to match the molecules in List-I with the corresponding bond enthalpies in List-II. This involves knowing the bond enthalpies commonly associated with these molecules. Let's match them one by one:
- HCl (Hydrochloric Acid): The typical bond enthalpy for HCl is approximately 431.0 kJ/mol. Therefore, HCl matches with Option (IV).
- N2 (Nitrogen Gas): Nitrogen molecules have a very strong triple bond, leading to a high bond enthalpy of approximately 946.0 kJ/mol. Therefore, N2 matches with Option (III).
- H2 (Hydrogen Gas): The bond enthalpy for H2 is typically around 435.8 kJ/mol. Thus, H2 matches with Option (I).
- O2 (Oxygen Gas): Oxygen molecules have a double bond with a bond enthalpy of approximately 498 kJ/mol. Hence, O2 matches with Option (II).
So, the correct matching of List-I with List-II is:
- (A) HCl matches with (IV) 431.0 kJ/mol
- (B) N2 matches with (III) 946.0 kJ/mol
- (C) H2 matches with (I) 435.8 kJ/mol
- (D) O2 matches with (II) 498 kJ/mol
Thus, the correct option is: A-IV, B-III, C-I, D-II.