Step 1: Analyze the plant diseases and their causative organisms.
- Karnal Bunt (P) is caused by Neovossia indica (III) and affects Rye (d).
- Ergot (Q) is caused by Claviceps purpurea (V) and affects Barley (c).
- Late blight (R) is caused by Phytophthora infestans (I) and affects Potato (b).
- Powdery mildew (S) is caused by Blumeria graminis (II) and affects Wheat (e).
Step 2: Conclusion.
Based on the above analysis, the correct matching is (C) P-III-d, Q-V-c, R-I-b, S-II-e.