Concept:
For a discrete random variable \(X\),
\[
\mu=E(X)=\sum xP(X=x),
\]
and the variance is defined as
\[
\operatorname{Var}(X)=E[(X-\mu)^2].
\]
Expanding this expression gives the standard formula
\[
\operatorname{Var}(X)=E(X^2)-[E(X)]^2.
\]
Step 1: Write the expression for the second moment.
The second moment about the origin is
\[
E(X^2)=\sum x^2P(X=x).
\]
Step 2: Use the variance formula.
Since
\[
\operatorname{Var}(X)=E(X^2)-[E(X)]^2,
\]
and
\[
E(X)=\mu,
\]
we obtain
\[
\operatorname{Var}(X)
=
\sum x^2P(X=x)-\mu^2.
\]
Hence,
\[
\boxed{\operatorname{Var}(X)=\sum x^2P(X=x)-\mu^2.}
\]
Therefore, the correct option is
\[
\boxed{(C)\;\sum x^2P(X=x)-\mu^2.}
\]