Let \[ x_1 = a, \quad x_2 = ar, \quad x_3 = ar^2, \quad x_4 = ar^3 \] Given that \[ a - 2, \quad ar - 7, \quad ar^2 - 9, \quad ar^3 - 5 \] are in A.P. Hence, \[ a_2 - a_1 = a_3 - a_2 \] \[ (ar - 7) - (a - 2) = (ar^2 - 9) - (ar - 7) \] \[ a(r - 1) - 5 = ar(r - 1) - 2 \] \[ a(r - 1)(r - 1) = -3 \quad \text{...(i)} \] Also, \[ a_2 - a_1 = a_4 - a_3 \] \[ (ar - 7) - (a - 2) = (ar^3 - 5) - (ar^2 - 9) \] \[ a(r - 1) - 5 = ar^2(r - 1) + 4 \] \[ a(r - 1)(r^2 - 1) = -9 \quad \text{...(ii)} \] Dividing (ii) by (i): \[ \frac{a(r - 1)(r^2 - 1)}{a(r - 1)(r - 1)} = \frac{-9}{-3} \] \[ r + 1 = 3 \Rightarrow r = 2 \] Substituting in (i): \[ a(1)(1) = -3 \Rightarrow a = -3 \] Thus, \[ x_1 = -3, \quad x_2 = -6, \quad x_3 = -12, \quad x_4 = -24 \] Now, \[ \frac{1}{24}(x_1 \cdot x_2 \cdot x_3 \cdot x_4) = \frac{1}{24}(-3)(-6)(-12)(-24) = 216 \] \[ \boxed{216} \]
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,