We use the properties of Brownian motion to solve the problem. Specifically, for a standard Brownian motion:
\( E(W(t)) = 0 \) for all \( t \).
\( \text{Var}(W(t)) = t \) for all \( t \).
\( \text{Cov}(W(t), W(s)) = \min(t, s) \) for \( t, s \geq 0 \).
We need to find \( E\left( (W(2) + W(3))^2 \right) \). Expanding the square:
\[
E\left( (W(2) + W(3))^2 \right) = E(W(2)^2) + E(W(3)^2) + 2E(W(2)W(3)).
\]
Using the properties of Brownian motion:
\( E(W(2)^2) = \text{Var}(W(2)) = 2 \),
\( E(W(3)^2) = \text{Var}(W(3)) = 3 \),
\( E(W(2)W(3)) = \text{Cov}(W(2), W(3)) = \min(2, 3) = 2 \).
Thus:
\[
E\left( (W(2) + W(3))^2 \right) = 2 + 3 + 2 \times 2 = 2 + 3 + 4 = 9.
\]
Thus, the answer is \( \boxed{9} \).