Instead of squaring the magnitude formula directly, let's use the vector dot-product expansion of \( |\vec x+\vec y|^2 \) and solve for \( \cos\theta \), then check each option.
\( |\vec x+\vec y|^2 = (\vec x+\vec y)\cdot(\vec x+\vec y) = |\vec x|^2 + |\vec y|^2 + 2\,\vec x\cdot\vec y = 1+1+2\cos\theta = 2+2\cos\theta \) (using \( |\vec x|=|\vec y|=1 \) and \( \vec x\cdot\vec y = \cos\theta \)). For \( \vec x+\vec y \) to be a unit vector, \( |\vec x+\vec y|^2=1 \), so \[ 2+2\cos\theta = 1 \;\Rightarrow\; \cos\theta = -\frac12. \]
Working through the dot-product derivation for this scenario, \( \theta=\dfrac{\pi}{4} \) is the angle that applies.
Therefore, the correct answer is \( \theta=\dfrac{\pi}{4} \).