Let \( \mathbf{a}, \mathbf{b} \) be two unit vectors. If \( \mathbf{c} = \mathbf{a} + 2\mathbf{b} \) and \( \mathbf{d} = 5\mathbf{a} - 4\mathbf{b} \) are perpendicular to each other, find the angle between \( \mathbf{a} \) and \( \mathbf{b} \).
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For perpendicular vectors \( \mathbf{c} \cdot \mathbf{d} = 0 \), expand and solve for \( \cos \theta \).