Concept:
For a piecewise-defined function,
\[
\mathcal{L}\{f(t)\}
=
\int_0^\infty e^{-st}f(t)\,dt.
\]
Since \(f(t)=0\) for \(t>\pi\),
\[
\mathcal{L}\{f(t)\}
=
\int_0^\pi e^{-st}\sin t\,dt.
\]
Also,
\[
\int e^{-st}\sin t\,dt
=
\frac{e^{-st}(-s\sin t-\cos t)}{s^2+1}.
\]
Step 1: Evaluate the Laplace transform.
\[
F(s)
=
\int_0^\pi e^{-st}\sin t\,dt.
\]
Using the standard integral,
\[
F(s)
=
\left[
\frac{e^{-st}(-s\sin t-\cos t)}
{s^2+1}
\right]_0^\pi.
\]
Step 2: Substitute the limits.
Since
\[
\sin\pi=0,\qquad
\cos\pi=-1,
\]
the upper limit becomes
\[
\frac{e^{-\pi s}}{s^2+1}.
\]
Also,
\[
\sin0=0,\qquad
\cos0=1,
\]
the lower limit becomes
\[
-\frac{-1}{s^2+1}
=
-\left(-\frac{1}{s^2+1}\right)
=
\frac{1}{s^2+1}.
\]
Therefore,
\[
F(s)
=
\frac{e^{-\pi s}+1}{s^2+1}.
\]
Hence,
\[
\boxed{
\mathcal{L}\{f(t)\}
=
\frac{e^{-\pi s}+1}{s^2+1}
}.
\]
Therefore, the correct option is
\[
\boxed{(C)\;
\dfrac{e^{-\pi s}+1}{s^2+1}.}
\]