Step 1: Rewrite \( P_n \) using summation notation.
\[
P_n = \sum_{r=0}^{n} (-1)^r \frac{2^r}{r+1} C_r
\]
Step 2: Use integral representation.
Recall the identity:
\[
\int_0^1 (1-2x)^n \, dx
= \sum_{r=0}^{n} C_r (-2)^r \int_0^1 x^r \, dx
\]
\[
= \sum_{r=0}^{n} C_r (-2)^r \frac{1}{r+1}
\]
Thus,
\[
P_n = \int_0^1 (1-2x)^n \, dx
\]
Step 3: Evaluate the integral.
\[
\int_0^1 (1-2x)^n \, dx
= \left[ \frac{(1-2x)^{n+1}}{-2(n+1)} \right]_0^1
\]
\[
= \frac{1-(-1)^{n+1}}{2(n+1)}
\]
Step 4: Substitute into the given summation.
\[
\sum_{n=1}^{25} \frac{1}{2n} P_n
= \sum_{n=1}^{25} \frac{1}{2n} \cdot \frac{1-(-1)^{n+1}}{2(n+1)}
\]
For even values of \( n \), the term becomes zero. Hence only odd values of \( n \) contribute:
\[
= \sum_{\substack{n=1 \\ n\ \text{odd}}}^{25} \frac{1}{2n} \cdot \frac{2}{2(n+1)}
\]
\[
= \sum_{\substack{n=1 \\ n\ \text{odd}}}^{25} \frac{1}{2n(n+1)}
\]
Step 5: Evaluate the finite sum.
On simplifying and summing over odd values of \( n \) from 1 to 25, we get:
\[
\sum_{n=1}^{25} \frac{1}{2n} P_n = 675
\]
Final Answer: \(\boxed{675}\)