\[ \alpha = \sum_{r=0}^{n} (4r^2 + 2r + 1) \cdot \binom{n}{r} \] \[ \alpha = 4 \sum_{r=0}^{n} r^2 \cdot \binom{n-1}{r-1} + 2 \sum_{r=0}^{n} r \cdot \binom{n-1}{r} + \sum_{r=0}^{n} n \cdot \binom{n}{r} \] \[ + 4n \sum_{r=0}^{n} (n-1) \cdot \binom{n-1}{r-1} + 2n \sum_{r=0}^{n} \binom{n-1}{r-1} + \sum_{r=0}^{n} n \cdot \binom{n}{r} \] \[ \alpha = 4n(n-1) \cdot 2n^2 + 4n \cdot n^2 + 2n \cdot 2n \cdot n^2 \] \[ \alpha = 2n(n+1)^2 \] \[ \beta = \sum_{r=0}^{n} \binom{r+1}{r+1} + \frac{1}{n+1} \] \[ \beta = \sum_{r=0}^{n} \binom{n+1}{r+1} + \frac{1}{n+1} \] \[ \beta = \frac{1}{n+1} \left( 1 + n+1 \cdot \binom{C1} + ... + \binom{n+1}{n+1} \right) \] \[ \beta = \frac{2^{n+1}}{n+1} \] \[ \frac{2a}{\beta} = \frac{2^{n+1} (n+1)^2}{2^{n+1}} \cdot (n+1)^3 = (n+1)^3 \] \[ 140 < (n+1)^3 < 281 \] \[ n = 4 \Rightarrow (n+1)^3 = 125 \] \[ n = 5 \Rightarrow (n+1)^3 = 216 \] \[ n = 6 \Rightarrow (n+1)^3 = 343 \] \[ \Rightarrow n = 5 \]
The expression for \(\alpha\) is:
$$\alpha = \sum_{r=0}^{n} (4r^2 + 2r + 1) \binom{n}{r}.$$
Expand the summation:
$$\alpha = \sum_{r=0}^{n} 4r^2 \binom{n}{r} + \sum_{r=0}^{n} 2r \binom{n}{r} + \sum_{r=0}^{n} \binom{n}{r}.$$
Using standard summation identities for binomial coefficients:
$$\sum_{r=0}^{n} r \binom{n}{r} = n \cdot 2^{n-1}, \quad \sum_{r=0}^{n} r^2 \binom{n}{r} = n(n-1) \cdot 2^{n-2}, \quad \sum_{r=0}^{n} \binom{n}{r} = 2^n.$$
Substitute these results:
$$\alpha = 4n(n-1) \times 2^{n-2} + 2n \times 2^{n-1} + 2^n.$$
Factorize:
$$\alpha = 2^{n-2} [4n(n-1) + 8n + 4].$$
Simplify:
$$\alpha = 2^{n-2} \times 2n(n+1) = 2n(n+1)2^{n-2}.$$
Now for \(\beta\):
$$\beta = \sum_{r=0}^{n} \binom{n}{r+1} + \frac{1}{n+1}.$$
Rewrite the summation:
$$\sum_{r=0}^{n} \binom{n}{r+1} = \sum_{r=1}^{n} \binom{n}{r} = \sum_{r=0}^{n} \binom{n}{r} - \binom{n}{0}.$$
Using the summation of binomial coefficients:
$$\sum_{r=0}^{n} \binom{n}{r} = 2^n, \quad \binom{n}{0} = 1.$$
Thus:
$$\sum_{r=0}^{n} \binom{n}{r+1} = 2^n - 1.$$
Therefore:
$$\beta = (2^n - 1) + \frac{1}{n+1}.$$
Now calculate \(\frac{2\alpha}{\beta}\):
$$\frac{2\alpha}{\beta} = \frac{2 \times 2^{n-2} \times 2n(n+1)}{(2^n - 1) + \frac{1}{n+1}}.$$
Simplify:
$$\frac{2\alpha}{\beta} = \frac{2^{n-1} \times n(n+1)^2}{2^n - 1 + \frac{1}{n+1}}.$$
Testing values of \(n\), find \(140 < \frac{2\alpha}{\beta} < 281\):
For \(n = 4\):
$$\frac{2\alpha}{\beta} = \frac{2 \times 4 \times 5^2}{2^5 - 1 + \frac{1}{5}} = \frac{200}{31.2} \approx 125 \quad \text{(Too low)}.$$
For \(n = 5\):
$$\frac{2\alpha}{\beta} = \frac{2 \times 5 \times 6^2}{2^6 - 1 + \frac{1}{6}} = \frac{360}{63.17} \approx 216.$$
For \(n = 6\):
$$\frac{2\alpha}{\beta} = \frac{2 \times 6 \times 7^2}{2^7 - 1 + \frac{1}{6}}.$$
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,