
Consider rectangle \(ABCD\) inscribed within rectangle \(PQRS\) as shown in the figure. Let \(\theta\) be the angle formed between side \(AB\) of \(ABCD\) and side \(PQ\) of \(PQRS\).
Using trigonometry, the dimensions of \(PQRS\) are expressed as:
\[ a = 4 \cos \theta + 2 \sin \theta \] \[ b = 2 \cos \theta + 4 \sin \theta \]
The area of \(PQRS\) is given by:
\[ \text{Area} = (4 \cos \theta + 2 \sin \theta)(2 \cos \theta + 4 \sin \theta) \]
Expanding this, we get:
\[ = 8 \cos^2 \theta + 16 \sin \theta \cos \theta + 4 \sin^2 \theta + 8 \sin^2 \theta \] \[ = 8 + 10 \sin 2\theta \]
The area is maximized when \(\sin 2\theta = 1\), i.e., \(\theta = 45^\circ\).
Thus, the maximum area is:
\[ 8 + 10 = 18 \]
Now, we calculate \((a + b)^2\):
\[ (a + b)^2 = (4 \cos \theta + 2 \sin \theta + 2 \cos \theta + 4 \sin \theta)^2 \] \[ = (6 \cos \theta + 6 \sin \theta)^2 \] \[ = 36(\sin \theta + \cos \theta)^2 \]
Since \(\sin \theta + \cos \theta = \sqrt{2}\) at \(\theta = 45^\circ\),\[ = 36(\sqrt{2})^2 = 36 \times 2 = 72 \]
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)