Concept:
Colouring agents are used in pharmaceutical preparations to improve appearance, identification, and patient acceptability. These colouring agents may be broadly classified as:
• Natural colouring agents
• Synthetic colouring agents
Step 1: Understanding the question.
The question asks for a natural colouring agent. Therefore, we must identify which option is obtained naturally and is commonly used as a colourant.
Step 2: Checking each option.
Tartrazine is a synthetic yellow dye. It is not a natural colouring agent.
Sunset yellow is also a synthetic azo dye. It is commonly used as an artificial colour.
Erythrosine is a synthetic red dye. It is not a natural colouring agent.
Caramel is obtained by controlled heating of carbohydrates or sugars. Hence, it is considered a natural colouring agent.
Step 3: Final selection.
Among the given options, only Caramel is a natural colouring agent.
\[
\boxed{\text{Caramel}}
\]