Extractive distillation is used when components have close boiling points or low relative volatility.
In this method, a high boiling solvent is added to the mixture.
The solvent changes the relative volatility of the components.
This makes separation easier.
The solvent does not usually form an azeotrope with the components.
It selectively interacts with one component more than the other.
As a result, volatility difference increases.
Flash distillation is a single-stage separation.
Steam distillation uses steam to reduce partial pressure and distill high boiling materials.
Azeotropic distillation uses an entrainer to form an azeotrope.
Therefore, the distillation in which solvent is added to alter relative volatility is:
\[
\text{Extractive distillation}
\]