Concept:
When a line is drawn parallel to one side of a triangle, it divides the other two sides proportionally. This is called the Basic Proportionality Theorem (BPT) or Thales' Theorem.
If:
\[
DE \parallel BC
\]
then:
\[
\frac{AD}{DB} = \frac{AE}{EC}
\]
Also, another useful proportional form is:
\[
\frac{AD}{AB} = \frac{AE}{AC}
\]
This form becomes easier when the entire side length is given.
Step 1: Understand the given ratio.
We are given:
\[
\frac{AD}{DB} = \frac{2}{3}
\]
This means side \(AB\) is divided into two parts in the ratio \(2:3\).
So we may assume:
\[
AD = 2k,\quad DB = 3k
\]
Therefore:
\[
AB = AD + DB = 2k + 3k = 5k
\]
Thus:
\[
\frac{AD}{AB} = \frac{2k}{5k} = \frac{2}{5}
\]
Step 2: Apply proportionality theorem.
Since:
\[
DE \parallel BC
\]
we use:
\[
\frac{AD}{AB} = \frac{AE}{AC}
\]
Substitute known values:
\[
\frac{2}{5} = \frac{AE}{2.5}
\]
Step 3: Solve for \(AE\).
Cross multiply:
\[
5 \times AE = 2 \times 2.5
\]
\[
5AE = 5
\]
Divide both sides by 5:
\[
AE = 1
\]
Step 4: Verification step.
Since:
\[
AC = 2.5
\]
then:
\[
EC = 2.5 - 1 = 1.5
\]
Now check ratio:
\[
\frac{AE}{EC} = \frac{1}{1.5} = \frac{2}{3}
\]
which matches:
\[
\frac{AD}{DB} = \frac{2}{3}
\]
Hence answer is verified.
Final Answer:
\[
\boxed{1 \text{ cm}}
\]