Step 1: In every nuclear reaction the total mass number (top numbers) and the total atomic number (bottom numbers) are conserved on both sides.
Step 2: Balance the mass numbers. Left side: \( 4 + A \). Right side: \( (A+3) + A_W \). So \[ 4 + A = (A+3) + A_W \ \Rightarrow\ A_W = 4 + A - A - 3 = 1. \]
Step 3: Balance the atomic numbers. Left side: \( 2 + Z \). Right side: \( (Z+2) + Z_W \). So \[ 2 + Z = (Z+2) + Z_W \ \Rightarrow\ Z_W = 0. \]
Step 4: Particle W has mass number 1 and charge 0, i.e. \( {}_{0}^{1}n \), which is a neutron. Hence option 4. A proton would have charge \( +1 \), an electron/positron mass number 0, so they are ruled out.
\[\boxed{W = {}_{0}^{1}n\ (\text{neutron})}\]