

n-alkanes on heating in this presence of anhydrous A1Cl3 and hydrogen chloride gas isomerise to branched chain alkanes.
The major product has one methyl side chain.
Calculate the potential for half-cell containing 0.01 M K\(_2\)Cr\(_2\)O\(_7\)(aq), 0.01 M Cr\(^{3+}\)(aq), and 1.0 x 10\(^{-4}\) M H\(^+\)(aq).

Two positively charged particles \(m_1\) and \(m_2\) have been accelerated across the same potential difference of 200 keV. Given mass of \(m_1 = 1 \,\text{amu}\) and \(m_2 = 4 \,\text{amu}\). The de Broglie wavelength of \(m_1\) will be \(x\) times that of \(m_2\). The value of \(x\) is _______ (nearest integer). 