
Temperature of surrounding \(=\) \(20ºC\)
For \(0\) to \(6\) minutes, average temp. \(=\) \(70ºC\)
Rate of cooling \(∝70ºC – 20ºC = 50ºC\)
For \(6\) to \(t_2\) minutes, average temp. \(= 50ºC\)
Rate of cooling \(∝30ºC\)
\(⇒ t_2-6 = \frac 53\) (\(6\) minutes)
\(⇒ t_2= 16 \) minutes
So, the answer is \(16\) minutes.
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
Newton’s law of cooling states that the rate of heat loss from a body is directly proportional to the difference in temperature between the body and its surroundings.
Let a body of mass m, with specific heat capacity s, is at temperature T2 and T1 is the temperature of the surroundings.
If the temperature falls by a small amount dT2 in time dt, then the amount of heat lost is,
dQ = ms dT2
The rate of loss of heat is given by,
dQ/dt = ms (dT2/dt) ……..(2)
Compare the equations (1) and (2) as,
– ms (dT2/dt) = k (T2 – T1)
Rearrange the above equation as:
dT2/(T2–T1) = – (k / ms) dt
dT2 /(T2 – T1) = – Kdt
where K = k/m s
Integrating the above expression as,
loge (T2 – T1) = – K t + c
or
T2 = T1 + C’ e–Kt
where C’ = ec