Step 1: Recall the working principle of a mass spectrometer.
A mass spectrometer separates ions according to their
\[
\boxed{\frac{m}{z}}
\]
value, where
- \(m\) = mass of the ion,
- \(z\) = charge on the ion.
Step 2: Identify the correct option.
Since ions with different mass-to-charge ratios follow different paths,
\[
\boxed{\text{Mass-to-charge ratio}}
\]
is the correct answer.
Therefore,
\[
\boxed{(A)}
\]
is the correct answer.