Concept:
A system of linear equations has infinitely many solutions when:
\[
\text{Rank}(A)=\text{Rank}(A|B)<\text{number of variables}
\]
This means one equation must be a linear combination of the others.
Hence, for infinitely many solutions, the third equation must be dependent on the first two equations.
Step 1: Write the given equations.
\[
2x+3y-3z=3 \qquad \cdots (1)
\]
\[
x+2y+\alpha z=1 \qquad \cdots (2)
\]
\[
2x-y+z=\beta \qquad \cdots (3)
\]
Since infinitely many solutions exist, equation (3) must be obtainable from equations (1) and (2).
Assume:
\[
(3)=\lambda(1)+\mu(2)
\]
Step 2: Compare coefficients of \(x\), \(y\), and constants.
From coefficient of \(x\):
\[
2\lambda+\mu=2
\qquad \cdots (4)
\]
From coefficient of \(y\):
\[
3\lambda+2\mu=-1
\qquad \cdots (5)
\]
Solving (4) and (5):
From (4),
\[
\mu=2-2\lambda
\]
Substitute into (5):
\[
3\lambda+2(2-2\lambda)=-1
\]
\[
3\lambda+4-4\lambda=-1
\]
\[
-\lambda=-5
\]
\[
\lambda=5
\]
Then,
\[
\mu=2-2(5)
\]
\[
\mu=-8
\]
Step 3: Find the value of \(\alpha\).
Compare coefficients of \(z\):
From equation (3),
\[
1=\lambda(-3)+\mu(\alpha)
\]
Substitute \(\lambda=5,\ \mu=-8\):
\[
1=5(-3)-8\alpha
\]
\[
1=-15-8\alpha
\]
\[
16=-8\alpha
\]
\[
\alpha=-2
\]
Step 4: Find the value of \(\beta\).
Compare constants:
\[
\beta=3\lambda+1\mu
\]
Substitute values:
\[
\beta=3(5)+(-8)
\]
\[
\beta=15-8
\]
\[
\beta=7
\]
Step 5: Compute
\[
\frac{\alpha}{\beta}-\frac{\beta}{\alpha}
\]
Substitute:
\[
\frac{-2}{7}-\frac{7}{-2}
\]
\[
=-\frac{2}{7}+\frac{7}{2}
\]
Taking LCM \(=14\):
\[
=\frac{-4+49}{14}
\]
\[
=\frac{45}{14}
\]
Thus,
\[
\boxed{\frac{\alpha}{\beta}-\frac{\beta}{\alpha}=\frac{45}{14}}
\]
Hence, the correct option is:
\[
\boxed{(B)\ \frac{45}{14}}
\]