To find the root mean square velocity of oxygen at the same temperature and pressure, we use the formula for root mean square velocity, which is given by:
\(v_{\text{rms}} = \sqrt{\frac{3kT}{m}}\)
where \(k\) is the Boltzmann's constant, \(T\) is the absolute temperature, and \(m\) is the mass of the molecule.
We know that the root mean square velocity for hydrogen is given as 2 km/s. Let this be \(v_{\text{rms, H}_2}\) and for oxygen it will be \(v_{\text{rms, O}_2}\).
We use the relation between the root mean square velocities and the molar masses:
\(\frac{v_{\text{rms, H}_2}}{v_{\text{rms, O}_2}} = \sqrt{\frac{M_{\text{O}_2}}{M_{\text{H}_2}}}\)
Where:
Substituting the values, we get:
\(\frac{2}{v_{\text{rms, O}_2}} = \sqrt{\frac{32}{2}}\)
\(\frac{2}{v_{\text{rms, O}_2}} = \sqrt{16}\)
\(\frac{2}{v_{\text{rms, O}_2}} = 4\)
Solving for \(v_{\text{rms, O}_2}\):
\(v_{\text{rms, O}_2} = \frac{2}{4} = 0.5 \text{ km/s}\)
Hence, the root mean square velocity of oxygen at the same condition is 0.5 km/s.
Given: - Root mean square (rms) velocity of hydrogen (\(v_{H_2}\)) = 2 km/s - Molecular mass of hydrogen (\(M_{H_2}\)) = 2 g/mol - Molecular mass of oxygen (\(M_{O_2}\)) = 32 g/mol
The root mean square velocity of a gas is given by:
\[ v_{\text{rms}} \propto \frac{1}{\sqrt{M}} \]
where \(M\) is the molar mass of the gas.
Using the inverse square root relationship for hydrogen and oxygen:
\[ \frac{v_{O_2}}{v_{H_2}} = \sqrt{\frac{M_{H_2}}{M_{O_2}}} \]
Substituting the given values:
\[ \frac{v_{O_2}}{2} = \sqrt{\frac{2}{32}} \] \[ \frac{v_{O_2}}{2} = \sqrt{\frac{1}{16}} \] \[ \frac{v_{O_2}}{2} = \frac{1}{4} \]
Multiplying both sides by 2:
\[ v_{O_2} = \frac{1}{4} \times 2 = 0.5 \, \text{km/s} \]
The root mean square velocity of oxygen at the same conditions is 0.5 km/s.
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)