1. From the given probability distribution, the total probability must equal 1:
\[ \sum P_i = 1 \implies a + 2a + a + b + 2b + 3b = 1. \]
Simplify:
\[ 4a + 6b = 1 \quad \cdots \text{(I)} \]
2. The mean is given by:
\[ E(X) = \sum P_i X_i = \frac{46}{9}. \]
Substitute the probabilities:
\[ E(X) = 0 \times a + 2 \times 2a + 4 \times (a + b) + 6 \times 2b + 8 \times 3b. \]
Simplify:
\[ 4a + 4b + 12b + 24b = \frac{46}{9}, \]
\[ 8a + 40b = \frac{46}{9} \quad \cdots \text{(II)}. \]
3. Solve equations (I) and (II) simultaneously: From (I): \(b = \frac{1}{9} - \frac{2a}{3}\). Substitute \(b = \frac{1}{9}\) and solve to find:
\[ a = \frac{1}{12}, \quad b = \frac{1}{9}. \]
4. Variance is calculated as:
\[ \text{Variance} = E(X^2) - (E(X))^2. \]
Step 1: Find \(E(X^2)\):
\[ E(X^2) = \sum P_i X_i^2 = 0^2 \times a + 2^2 \times 2a + 4^2 \times (a + b) + 6^2 \times 2b + 8^2 \times 3b. \]
Simplify:
\[ E(X^2) = 4a + 16(a + b) + 72b + 192b. \]
Substitute \(a = \frac{1}{12}, b = \frac{1}{9}\):
\[ E(X^2) = \frac{298}{9}. \]
Step 2: Find \((E(X))^2\):
\[ (E(X))^2 = \left(\frac{46}{9}\right)^2 = \frac{2116}{81}. \]
Step 3: Calculate variance:
\[ \text{Variance} = \frac{298}{9} - \frac{2116}{81} = \frac{566}{81}. \]
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,